Claims
| Claim | Type | Assessment | Score | Review checks | References |
|---|---|---|---|---|---|
| Under the reported optimized photochemical conditions, the iron complex produced ammonium in 85% yield, and the study reported a maximum turnover number of 10,000 for the catalyst variant ICF3-OTf, with a scaled experiment at 0.001 mol% catalyst giving a turnover number of 5,000. | QUANTITATIVE | Supported | 0.8808 | 1 of 4 | 83 |
| Under the reported thermal catalytic conditions, the iron complex converted nitrate to nitric oxide with a measured 68% yield in the trapping experiment. | QUANTITATIVE | Supported | 0.8808 | 1 of 4 | 81 |
| In the study, appending aniline hydrogen-bond donors to a zinc tris(2-pyridylmethyl)amine complex increased first-event nitrate binding affinity from 0.18 ± 0.04 M−1 to (1.5 ± 0.6) × 10^6 M−1, a difference of about seven orders of magnitude. | QUANTITATIVE | Supported | 0.8808 | 1 of 4 | 82 |