Claims
| Claim | Type | Assessment | Score | Review checks | References |
|---|---|---|---|---|---|
| Replacing zinc with iron in the hydrogen-bonded ligand system enabled catalytic nitrate reduction under thermal and photochemical conditions, producing nitric oxide thermally and ammonia photochemically with high turnover numbers. | COMPARATIVE | Supported | 0.9911 | 1 of 4 | 120 |
| Appending aniline hydrogen-bond donors to a tris(2-pyridylmethyl)amine zinc complex increased nitrate binding affinity by up to seven orders of magnitude relative to analogues lacking those secondary-sphere interactions. | QUANTITATIVE | Supported | 0.9861 | 1 of 4 | 95 |