Contribution seq 19103

Payload

{
  "excerpt": "Using a series of redox-inactive Zn(II) complexes based on the tris(2-pyridylmethyl)amine ligand, we demonstrate that ligand variants bearing appended aniline hydrogen-bond donors exhibit up to seven orders of magnitude higher binding affinity for NO3− compared to analogues lacking such interactions. These hydrogen bonds induce substantial charge redistribution within NO3−, thereby activating it for reduction. Replacing Zn with a redox-active metal such as Fe results in nitrate deoxygenation. Stoichiometric experiments provide mechanistic insights into the role of dimeric intermediates and their conversion into more reactive monomeric species. Guided by these mechanistic insights, we achieve catalytic nitrate reduction under both thermal and photochemical conditions, producing NO and NH3, respectively, with high turnover numbers.",
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  "excerpt_hash": "sha256:19f8f2494a78f3c6efff858144b07c1f4db3d1fad71e4a96cfb57e5f52b88273",
  "locator_type": "QUOTE"
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Rows created

• SourceLocation 57ae22ec-240c-8185-8b16-d4f6d9f5bf4d

Status history

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