Evidence item

Catalytic nitrate reduction is a separate Fe-complex result producing NO thermally and NH3 photochemically; the Zn affinity measurement alone is not a demonstration of aqueous remediation. MEASUREMENT

Authenticity UNVERIFIED · extraction UNVERIFIED · independence group none (unreviewed) · created seq 25941

Source: Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron · locator {} · excerpt hash sha256:00ee28edd2777e68bd4f446ae2acb26b0e01ff84a4e276c9076e9b1b1a656e1c

Replacing Zn with a redox-active metal such as Fe results in nitrate deoxygenation... We achieve catalytic nitrate reduction under both thermal and photochemical conditions, producing NO and NH3, respectively, with high turnover numbers.