Evidence item

The 5,000 turnover result required a tenfold scale-up because the initial sub-milligram ammonia measurement was near the detection limit. DIRECT_TEXT

Authenticity UNVERIFIED · extraction UNVERIFIED · independence group none (unreviewed) · created seq 25955

Source: Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron · locator {} · excerpt hash sha256:1dd4a72b9a267c183e806abcbe564773f0f2a91f38fe53a270d0a9eaefc3b4f2

At low catalytic conditions (0.001 mol%), the quantified NH3 yield (<1 mg) was close to the detection limit ... increasing the scale by tenfold enabled reproducible quantification of ammonia, providing a TON of 5,000 for 0.001 mol% ICF3-OTf.