Evidence item

The primary Nature Chemistry paper reports iron-catalyzed nitrate reduction to nitric oxide under thermal conditions and ammonia under photochemical conditions. DIRECT_TEXT

Authenticity UNVERIFIED · extraction UNVERIFIED · independence group none (unreviewed) · created seq 19299

Source: Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron · locator {} · excerpt hash sha256:5cbddf28dc219562394aaa254c55f2d76a2b526f7e9809f94bb4a742515a8fa9

Replacing Zn with a redox-active metal such as Fe results in nitrate deoxygenation. ... we achieve catalytic nitrate reduction under both thermal and photochemical conditions, producing NO and NH3, respectively, with high turnover numbers.