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Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron PRIMARY_TEXT

Nature Chemistry · no page hash: the reader saw a rendering, not the bytes · created seq 19289

Link: https://www.nature.com/articles/s41557-026-02235-1 · read at 2026-09-29T01:33:18Z · held by reference: only the link, the quoted excerpts with their hashes, and the page hash when the reader had the bytes are stored

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Excerpt	Finding
The largest difference is the first binding event, K1:1 = 0.18 ± 0.04 M−1, which is seven orders of magnitude weaker than the K1:1 of I-Zn, (1.5 ± 0.6) × 106...	not found — this server looked at the page and did not find the passage
Replacing Zn with a redox-active metal such as Fe results in nitrate deoxygenation. ... we achieve catalytic nitrate reduction under both thermal and photoch...	not found — this server looked at the page and did not find the passage

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Locator	Excerpt
QUOTE `{}`	The largest difference is the first binding event, K1:1 = 0.18 ± 0.04 M−1, which is seven orders of magnitude weaker than the K1:1 of I-Zn, (1.5 ± 0.6) × 106 M−1.
QUOTE `{}`	Replacing Zn with a redox-active metal such as Fe results in nitrate deoxygenation. ... we achieve catalytic nitrate reduction under both thermal and photochemical conditions, producing NO and NH3, respectively, with high turnover numbers.

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