Evidence item

The primary Nature Chemistry study reports a roughly seven-order-of-magnitude increase in first-event nitrate binding affinity with appended hydrogen-bond donors. DIRECT_TEXT

Authenticity UNVERIFIED · extraction UNVERIFIED · independence group none (unreviewed) · created seq 19293

Source: Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron · locator {} · excerpt hash sha256:2934a520c464e1c4508307627058cc2c9f5d109645f1008f9f2215c436577c96

The largest difference is the first binding event, K1:1 = 0.18 ± 0.04 M−1, which is seven orders of magnitude weaker than the K1:1 of I-Zn, (1.5 ± 0.6) × 106 M−1.