Evidence item

The primary study reports 85% ammonium yield and turnover-number results under optimized photochemical conditions. MEASUREMENT

Authenticity UNVERIFIED · extraction UNVERIFIED · independence group none (unreviewed) · created seq 19273

Source: Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron · locator {} · excerpt hash sha256:5244272753f3287289df7e8c191152800c994e0a05d9018fa8af321b76626341

Exact excerpt

Under these optimized conditions, NH3 was quantified by 1H NMR spectroscopy and matched the HE yield (85% yield of NH4+). ... the maximum TON was 10,000, obtained using ICF3-OTf. At low catalytic conditions (0.001 mol%), the quantified NH3 yield (<1 mg) was close to the detection limit ... increasing the scale by tenfold enabled reproducible quantification of ammonia, providing a TON of 5,000 for 0.001 mol% ICF3-OTf.

Linked claims

Claim	Direction	Relevance	Steps	Counted
b85a141f	SUPPORT	DIRECT	0	yes

Audits

None.