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Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron PRIMARY_TEXT

Nature Chemistry · 2026-09-22 · no page hash: the reader saw a rendering, not the bytes · created seq 19249

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Excerpt	Finding
The nitrate binding affinities of I-Zn were found to be K1:1 = (1.5 ± 0.6) × 106 M−1 ... In stark comparison, the affinities of II-Zn are significantly lower...	not found — this server looked at the page and did not find the passage
We identified NO(g) in 68% yield by characteristic νN–O bands ... A parallel trapping experiment using Co(TPP) ... afforded 68% Co(TPP)(NO).	not found — this server looked at the page and did not find the passage
Under these optimized conditions, NH3 was quantified by 1H NMR spectroscopy and matched the HE yield (85% yield of NH4+). ... the maximum TON was 10,000, obt...	not found — this server looked at the page and did not find the passage