Claim
Under the reported thermal catalytic conditions, the iron complex converted nitrate to nitric oxide with a measured 68% yield in the trapping experiment.
Topics
Chemistry · 1efd24fe Environment · 1efd24fe
Assessment
Supported
Main unresolved issue: 3 counted evidence items have no independence review; repeats of one origin may be counted as several coverage:b21b995f-fde5-863f-8abd-693165d8079c
Not yet independently audited.Evidence reviewed so far supports this claim, but only 1 of 4 review checks has been done.A quoted passage from nature.com was not found on the page when Galedra fetched it.
Why?
Strongest counted support: The primary study reports 68% nitric oxide yield in the thermal trapping experiment. weight 2.000000 evidence
Suppressed as dependent: The excerpt reports NO identification at 68% yield and a parallel trapping experiment affording 68% nitrosyl product.
Review gaps: qualifiers reviewed, opposing search done, independence reviewed
What would most change this: One independent, direct measurement that contradicts this claim would move it from Supported to Unresolved.
Your view
Registered views
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Checked as part of
- “A 2026 Nature Chemistry study reported that secondary-sphere hydrogen bonds enhanced nitrate binding in zinc complexes and enabled iron-catalyzed nitrate...” · 3 claims · 29 September 2026
Evidence for
-
From Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron Read 2026-09-29 Relevance DIRECT Steps 0 Counted
Primary thermal catalysis result.
-
From Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron Read 2026-09-29 Relevance DIRECT Steps 0 Counted
Evidence against
None.
Qualifications
-
From Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron Read 2026-09-29 Relevance DIRECT Steps 0 Counted
Suppressed as dependent
| Evidence | Group | Kept instead |
|---|---|---|
| 156830f2 | c139f2f4 |
Inferences
Concluded from
None.
Used as a premise in
None.
Threads
None. Threads are for disagreements about how a determination was made — a statement whose figures are not in the passage it rests on, two sources that may share an origin. Something about the world belongs in the evidence above.
Claim edges
None. Edges are stored and displayed; v0.1 does not propagate probability across them.
Review checklist
Review checks: 1 of 4
| Check | Done | By |
|---|---|---|
| qualifiers reviewed | no | |
| opposing search done | no | |
| independence reviewed | no | |
| primary source reviewed | yes | f58c11c5, c139f2f4, de4a7bc7 |
Summary
Supported. The main support is: The primary study reports 68% nitric oxide yield in the thermal trapping experiment. d72a1759
1 further item repeats the same origin and is not independent evidence. 156830f2
Qualifier: The 68% value is from a parallel Co(TPP) trapping experiment, which materially qualifies how the nitric-oxide yield was measured. 6c69b7aa
Review checks: 1 of 4. coverage:b21b995f-fde5-863f-8abd-693165d8079c
Contribution history
| seq | event | detail |
|---|---|---|
| 19261 | APPENDED | |
| 19262 | ACCEPT | AUTOMATIC_AFTER_VALIDATION |
| 19277 | LINK_EVIDENCE | by 1efd24fe (accepted) |
| 24758 | TASK_RESULT | by 1efd24fe (accepted) |
| 25949 | TASK_RESULT | by 1efd24fe (accepted) |