Galedra
Sign in Sign up

Topics · Science

Chemistry

As of snapshot 27745 under ledger-default@0.3.0. Counts by assessment state, descriptive only: no topic is scored. 1 Insufficient evidence3 Leans supported55 Supported

ClaimTypeAssessment
The study reported that mammalian cells can use S₈ to produce hydropersulfides that act as antioxidants.OBSERVATIONALSupported
A 2026 study detected cyclooctasulfur (S₈) in both mouse and human cells, with high levels in mitochondria and lipid droplets.OBSERVATIONALSupported
The report states that N-terminal sequence perturbations preserve the DILT hexagonal lattice while modulating pore hydration and surface chemistry.COMPARATIVESupported
Cryo-electron microscopy reportedly resolved DILT fibrils at 2.9–4.0 Å, with a repeating unit of 12 peptide chains and C6 symmetry.QUANTITATIVESupported
The DILT family of nine-residue amphiphilic peptides assembles into hexagonal nanofibrils with continuous approximately 5-nm solvent-accessible channels through cross-beta-dimer, trimeric-junction, and inversion motifs.OBSERVATIONALSupported
The study’s joint H2O and CO2 constraints favored near-equilibrium chemistry, approximately 10× solar metallicity, and a 3-sigma upper limit of C/O below 0.52.QUANTITATIVESupported
The study reported tentative retrieval evidence for H2S in HAT-P-1 b’s atmosphere, with log10 Bayes factor 1.4.QUANTITATIVESupported
The study reported strong retrieval evidence for H2O and CO2 in HAT-P-1 b’s atmosphere, with log10 Bayes factors of 8.9 and 52.3, respectively.QUANTITATIVESupported
In the study, water-derived hydroxyl-radical formation was identified as the rate-determining step in polyethylene oxidation, with a kH/kD isotope effect of 7.CAUSALSupported
The study achieved complete polyethylene conversion with nearly 69% selectivity to short-chain diacids and demonstrated scaling up to 300 g for mixed commercial plastics.QUANTITATIVESupported
The study reported a catalyst-free microdroplet-interface strategy using in situ hydroxyl radicals to oxidatively cleave diverse waste plastics into carboxylic acids under mild conditions.OBSERVATIONALSupported
The study's mechanistic investigations suggest that the deoxygenative functionalization begins with two-electron oxidative addition of a C–O bond to a low-valent chromium species, forming an organochromium intermediate.CAUSALLeans supported
The reported chromium-catalyzed strategy couples alcohols, ethers, and carbonyl compounds with electrophiles to produce organosilicon, organogermanium, organostannane, and organoboron compounds.OBSERVATIONALSupported
The reported perovskite photovoltaic minimodules retained 95.7% of their initial performance after 1000 one-hour thermal cycles between −65°C and 85°C.QUANTITATIVESupported
In the reported perovskite photovoltaic structure, an ultrathin conformal SnOx interlayer suppresses interfacial reactivity between NiOx and the perovskite.CAUSALLeans supported
The reported Li||S2Cl2 chemistry increased average operating voltage from 2.05 to 2.54 V, raised sulfur-specific capacity by 58%, and exceeded 1,700 Wh kg−1 electrode-level specific energy while cycling over 100 cycles.QUANTITATIVESupported
A free-chloride-rich ionic liquid electrolyte enables reversible Li||S2Cl2 battery chemistry that converts Li2S to S2Cl2 through a three-electron sulfur redox process.OBSERVATIONALSupported
The study reported that reef-building coral microbiomes had biosynthetic potential rivaling or surpassing traditional natural-product sources such as sponges.COMPARATIVELeans supported
The study measured a mean positive µ142Nd value of +3.2 ± 0.9 (2 s.e., n = 13) in Fani Maoré basanites.QUANTITATIVESupported
The study reported that fungal P450 enzymes PpnB and NseB catalyzed oxidative C(sp2)-methyl removal from O-prenyl l-tyrosine to produce O-homoallenyl l-tyrosine and O-but-2-ynyl l-tyrosine, respectively.OBSERVATIONALSupported
At 80 bar, the study measured CU-6 gravimetric methane uptakes of up to 0.67 g g−1 at 273 K and 0.53 g g−1 at 298 K for CU-6-Fe.QUANTITATIVESupported
At 100 bar and 77 K, the study measured total hydrogen uptakes of 17.5 wt% for CU-6-Fe and 15.9 wt% for CU-6-Cr, with volumetric uptakes near 45.4–45.5 g l−1.QUANTITATIVESupported
The study reported CU-6-Fe and CU-6-Cr with an interconnected hierarchical pore system and BET surface areas up to 7,145 m2 g−1.QUANTITATIVESupported
The study identified a TaEIL3–TaJAZ1–TaNPF7.6-A1 regulatory pathway affecting nitrogen-use efficiency in wheat.OBSERVATIONALSupported
ArmA is a glycosyl hydrolase specific for archaeal peptidoglycan, and the study found that it cleaves archaeal cell-wall material at the site of methanogen cell division.OBSERVATIONALInsufficient evidence
In the study’s mass-balance tests, the permissible carbonaceous CI contribution to the bulk silicate Earth was constrained below approximately 0.3% by ruthenium and below 2% by calcium.QUANTITATIVESupported
The study synthesized Imma-B60 through high-pressure formation of a Na4B60 precursor followed by sodium degassing.OBSERVATIONALSupported
The reported Imma-B60 boron allotrope exhibited approximately 23% plastic deformation through dislocation-mediated slip.QUANTITATIVESupported
The reported Imma-B60 boron allotrope had a bandgap below 0.2 eV and electrical conductivity of approximately 9 × 10^2 S m−1.QUANTITATIVESupported
Under the reported optimized photochemical conditions, the iron complex produced ammonium in 85% yield, and the study reported a maximum turnover number of 10,000 for the catalyst variant ICF3-OTf, with a scaled experiment at 0.001 mol% catalyst giving a turnover number of 5,000.QUANTITATIVESupported
Under the reported thermal catalytic conditions, the iron complex converted nitrate to nitric oxide with a measured 68% yield in the trapping experiment.QUANTITATIVESupported
In the study, appending aniline hydrogen-bond donors to a zinc tris(2-pyridylmethyl)amine complex increased first-event nitrate binding affinity from 0.18 ± 0.04 M−1 to (1.5 ± 0.6) × 10^6 M−1, a difference of about seven orders of magnitude.QUANTITATIVESupported
Replacing zinc with iron in the hydrogen-bonded ligand system enabled catalytic nitrate reduction under thermal and photochemical conditions, producing nitric oxide thermally and ammonia photochemically with high turnover numbers.COMPARATIVESupported
Appending aniline hydrogen-bond donors to a tris(2-pyridylmethyl)amine zinc complex increased nitrate binding affinity by up to seven orders of magnitude relative to analogues lacking those secondary-sphere interactions.QUANTITATIVESupported
For the three studied early galaxies, the reported gas metallicities were log(Zgas/Zsun) of −0.52, −0.85 and −0.78, respectively.QUANTITATIVESupported
The study demonstrated a monolithic perovskite–silicon tandem solar cell with certified power-conversion efficiency of 33.0%.QUANTITATIVESupported
Ambient-air, blade-coated perovskite solar cells in the study reached 26.5% certified power-conversion efficiency, while modules reached 23.2% and cells retained 99.8% of initial efficiency after 1,200 hours of light soaking.QUANTITATIVESupported
A 2.52-angstrom cryo-electron microscopy structure showed IMP-2380 bound to NorA in an outward-open conformation that occludes the substrate-binding cavity.OBSERVATIONALSupported
In a catalyst-design application, MatBrain generated 30,000 candidate structures and identified 38 promising materials within 48 hours.QUANTITATIVESupported
MatBrain is a dual-model crystal-materials research agent composed of a 30-billion-parameter analytical model and a 14-billion-parameter executive model.DEFINITIONALSupported
The study defines void suppression capability as the product of lithium full-stripping areal capacity and applied current density, and phase-field modelling predicts dendrite growth and cell failure when stripped capacity exceeds 70% of full depletion capacity.CAUSALSupported
In an all-solid-state lithium-anode study, Mg–1 wt% La inoculation increased critical current density/capacity from 1.2 mA cm−2/0.6 mAh cm−2 for LiMg to 2.2 mA cm−2/1.1 mAh cm−2 for LiMgLa, which sustained stable plating/stripping for over 1,200 hours at 0.7 mA cm−2 at room temperature.QUANTITATIVESupported
In the Nworie River assessment, gamma-chlordane had the highest detected concentration at 0.1704 mg/L, was detected at more than 60% of sampling sites above Federal Ministry of Environment limits, and Sites 4 and 5 were dual microplastic/OCP contamination hotspots.QUANTITATIVESupported
FTIR analysis of Nworie River samples identified 54 microplastic spectral signatures across four major polymer types—polyethylene, polypropylene, polystyrene, and polyvinyl chloride—with the highest polymer diversity at urban-transit Site 5 and suburban Site 4.QUANTITATIVESupported
C3X-5 treatment of cigar-tobacco leaves yielded 66 key differential volatile organic compounds and increased desirable pyrazine and ketone aroma compounds while suppressing 1-hexanal-associated green off-notes.QUANTITATIVESupported
In cigar-tobacco fermentation, Citrus reticulata-derived Bacillus C3X-5 inoculation increased amylase and protease activities, reduced sugar and free-amino-acid content, and directed microbial community succession while enriching functional genera such as Aspergillus.OBSERVATIONALSupported
In the reported laser-powder-bed-fused Ti–7.5Al–3.3Cr alloy, sub-10-nm hetero-stacking bands coincided with a measured yield strength of about 1.50 GPa, ultimate tensile strength of 1.73 GPa, and uniform elongation of about 7.5% in room-temperature tensile tests.QUANTITATIVESupported
In the reported Bayesian hybrid-accretion model, bulk silicate Mars reflected 27 ± 5% pebble-accreted material and 73 ± 5% Vesta-like planetesimal material.QUANTITATIVESupported
In the reported Bayesian hybrid-accretion model, bulk silicate Earth was best reproduced by at least 75% contribution from pebble-accreted protoplanets and up to about 25% Vesta-like planetesimal material.QUANTITATIVESupported
In the reported study, the perovskite solar devices retained 93.3% of their initial efficiency after 1000 hours of maximum-power-point tracking.QUANTITATIVESupported
In the reported study, flexible perovskite solar devices achieved 25.13% efficiency, while a 655.2 cm² submodule achieved 22.60% efficiency (certified 21.07%).QUANTITATIVESupported
In the reported hard-carbon preparation study, reducing carbonization temperature from 1300 °C to 900 °C was associated with 49.7% lower energy consumption and 47.5% lower carbon emissions.QUANTITATIVESupported
In the reported hard-carbon sodium-ion pouch-cell experiment, the cell achieved 208.1 Wh kg−1 specific energy at 1.5–4.3 V based on the entire cell.QUANTITATIVESupported
In the same experiments, the iron metal produced by hydrogen reduction strongly sequestered phosphorus, stripping it from the silicate.OBSERVATIONALSupported
In laboratory experiments melting anhydrous mafic lithologies in hydrogen streams, hydrogen reduction of iron oxide to iron metal generated large amounts of water within several hours.OBSERVATIONALSupported
NASA reported that Webb observations of the gas giant WD 1856 b detected methane signatures in its atmosphere while it orbited a white dwarf.OBSERVATIONALSupported
A Tohoku University Earth Science page reported that six sugars, including ribose and glucose, were detected in sand returned from asteroid Bennu.TEXTUALSupported
Analyses of samples returned from asteroid Bennu detected 14 of the 20 amino acids used by life on Earth to make proteins and all five canonical nucleobases.QUANTITATIVESupported
Demis Hassabis shared half of the 2024 Nobel Prize in Chemistry for developing AlphaFold2, an AI system for protein structure prediction.HISTORICALSupported